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From the liner notes

Season six of the hit TV series about the vampire slayer and her gang of friends.

Disc 1: "Bargaining", "After Life", "Flooded", commentary for "Bargaining" byMarti Nixon and David Fury

Disc 2: "Serial Life", "All the Way", "Once More With Feeling", "Tabula Rasa", commentary for "Once More With Feeling" by writer/director Joss Whedon, behind the scenes featurette, easter egg, music videos: "I've got a Theory/Bunnies/We're Together", "I'll Never Tell", "Walk Through the Fire"

Disc 3: "Smashed", "Wrecked", "Gone", commentary for "smashed" by Drew Z. Greenberg, Academy of Television Arts and Sciences panel discussion

Disc 4: "Doublemeat Palace", "Dead Things", "Older and Far Away", "As You Were", behind the scenes featurette, easter egg

Disc 5: "Hell's Bells", "Normal Again", "Entropy", "Seeing Red", commentary for "Hells Bells" by David Soloman and Rebecca Rand Kirshner, commentary for "Normal Again", by Rick Rosenthal and Diego Gutierrez

Disc 6: "Villians", "Two to Go", "Grave", commentary for "Grave" by James Contner and David Fury, 2 featurettes, outtakes, interactive game trailer, DVD-ROM